Strategy for enhanced thermoelectric performance of Bi2S3 nanorods by Bi nanoinclusions

Abstract

This is the first report on the enhanced thermoelectric (TE) properties of novel Bi2S3-Bi nanocomposites synthesized using a one-step polyol method at different reaction temperatures (TRe) and time. They are well-characterized as nanorod-composites, coexistent with orthorhombic Bi2S3 and rhombohedral Bi phases together in which the latter coats the former forming Bi2S3-Bi core-shell type structures along with independent Bi nanoparticles (NPs). There is a very significant observation of systematic reduction in electri-cal resistivity \r{ho} with reaction temperature and time duration increase, revealing a promising approach for reduction of \r{ho} in this highly resistive Bi2S3 and hence resolving the earlier obstacles for its thermoelectric application potentials for the past few decades. Most astonishingly, TE power factor at 300 K of highest Bi content nanocomposite pellet, made at 27 oC using ~900 MPa pressure, is 3 orders of magnitude greater than that of hot-pressed Bi2S3, or even 23% better than that of spark plasma-sintered core-shell Bi2S3@Bi sample reported earlier (Tarachand et al. Nano Res. 2016, 9, 3291; Ge et al. ACS Appl. Mater. Interfaces 2017, 9, 4828). Considering the probable greatly reduced thermal conductivity due to their complex nanostructures, the significantly improved TE performance potential near 300 K is highly anticipated for these toxic- and rare earth element-free TE nanocomposites, making the present synthesis method as a pioneering approach for developing enhanced thermoelectric properties of Bi2S3-based materials without using extra sintering steps.