Structure of amorphous Cu2GeTe3 and a model for its fast phase-change mechanism
Abstract
The structure of amorphous Cu2GeTe3 is investigated by a combination of anomalous x-ray scattering and extended x-ray absorption fine structure experiments. The experimental data are analyzed with a reverse Monte Carlo modeling procedure, and interpreted in terms of the short- and intermediate-range order. Based on this information, a model for the phase transition in Cu2GeTe3 is proposed, in which atoms move toward the center of the 6-fold rings of the crystal structure, leading to the formation of wrong bonds and a broader distribution of ring structures, but also preserving some structural motifs of the crystal.
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