Jarzynski Equality for Soret Equilibria -- Virtues of Virtual Potentials

Abstract

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains the dissipative switching process that can take the system far from equilibrium. Here, we demonstrate theoretically and experimentally that such a relation also holds for the nonisothermal case, where the initial stationary state is not in equilibrium and the switching is effected by dynamically changing temperature gradients instead of a conservative force. Our demonstration employs a single colloidal particle trapped by optically induced thermophoretic drift currents. It relies on identifying suitable equivalents of classical work and heat and our ability to measure their distributions and express them in terms of a virtual potential.