Accounting for the long-range forces in the model of hard sphere

Abstract

A method for taking into account the long-range potential of atoms in the framework of the hard-sphere model is proposed. It is shown that thermodynamic quantities can be represented as a sum of three contribution: that of an ideal gas, the interaction of hard sphere, and the long-range potential. In the leading approximation on density, the corrections to the virial coefficient and heat capacity due to the smooth component of the potential are calculated. Attention is drawn to the fact that the effects determined by the long-range part of of the potential can be described in the framework of the self-consistent field model.