Eu$^{2+}$: a suitable substituent for Pb$^{2+}$ in CsPbX$_3$ perovskite nanocrystals?

Abstract

Eu$^{2+}$ is used to replace toxic Pb$^{2+}$ in metal halide perovskite nanocrystals (NCs). The synthesis implies injection of cesium oleate into a solution of europium (II) bromide at an experimentally determined optimum temperature of 130C and a reaction time of 60s. Structural analysis indicates the formation of spherical CsEuBr$_3$ nanoparticles with a mean size of 43nm. Using EuI$_2$ instead of EuBr$_2$ leads to the formation of 18nm CsI nanoparticles, while EuCl$_2$ does not show any reaction with cesium oleate forming 80nm EuCl2 nanoparticles. The obtained CsEuBr3 NCs exhibit bright blue emission at 413nm (FWHM 30 nm) with a room temperature photoluminescence quantum yield of 39%. The emission originates from the Laporte-allowed 4f7-4f65d1 transition of Eu$^{2+}$ and shows a PL decay time of 263ns. The long-term stability of the optical properties is observed, making inorganic lead-free CsEuBr$_3$ NCs promising deep blue emitters for optoelectronics.