A unifying mechanism to explain the rate dependent rheological behavior in non-Brownian suspensions: One curve to unify them all

Abstract

We propose a unifying mechanism based on the Stribeck curve for the coefficient of friction between the particles to capture the shear thinning - Newtonian plateau - shear thickening - shear thinning rheological behavior at low - intermediate - beyond critical - high shear rates, respectively, for a typical dense non-Brownian suspension. We establish the accuracy of the proposed model by comparing the numerical results with experimental data. The presence of non-DLVO (Derjaguin and Landau, Verwey and Overbeek) forces and a coefficient of friction reducing with asperity deformation explain the existence of the Newtonian plateau at the intermediate shear rates and the second shear thinning regime at high shear rates, respectively.