Disorder-induced vibrational anomalies from crystalline to amorphous solids

Abstract

The origin of boson peak -- an excess of density of states over Debye's model in glassy solids -- is still under intense debate, among which some theories and experiments suggest that boson peak is related to van-Hove singularity. Here we show that boson peak and van-Hove singularity are well separated identities, by measuring the vibrational density of states of a two-dimensional granular system, where packings are tuned gradually from a crystalline, to polycrystals, and to an amorphous material. We observe a coexistence of well separated boson peak and van-Hove singularities in polycrystals, in which the van-Hove singularities gradually shift to higher frequency values while broadening their shapes and eventually disappear completely when the structural disorder $\eta$ becomes sufficiently high. By analyzing firstly the strongly disordered system ($\eta=1$) and the disordered granular crystals ($\eta=0$), and then systems of intermediate disorder with $\eta$ in between, we find that boson peak is associated with spatially uncorrelated random flucutations of shear modulus $\delta G/\langle G \rangle$ whereas the smearing of van-Hove singularities is associated with spatially correlated fluctuations of shear modulus $\delta G/\langle G \rangle$.