Magnetic properties and magnetocaloric effect of $\mathrm{Tb_2Rh_3Ge}$

Abstract

We report the structural, magnetic properties, and magnetocaloric effect of a new polycrystalline compound of $\mathrm{Tb_2Rh_3Ge}$. This present compound crystallizes with $\mathrm{Mg_2Ni_3Si}$-type of rhombohedral Laves phases (space group $R\overline{3}m$, hR18). The magnetic properties and magnetocaloric effect of the $\mathrm{Tb_2Rh_3Ge}$ is explored through dc-magnetization measurements. Temperature dependence of magnetization revealed that the compound exhibits ferromagnetic behavior with $T_C$$=$56 K. The field dependence of magnetization indicates that $\mathrm{Tb_2Rh_3Ge}$ is a soft ferromagnet. The obtained isothermal magnetic entropy changes ($\Delta S_m$), and refrigeration capacity (relative power cooling) for a change of magnetic field 0-9 T are 12.74 J/kg-K, and 497(680) J/kg respectively. The Arrott plots and universal curve of normalized $\Delta S_m$ indicate that this compound undergoes second order ferromagnetic phase transition