Interaction of Acoustic and Quasi-Elastic Modes in Liquid Water on Nanometer Length Scales

Abstract

We investigate the presence of an acoustic-quasi-elastic interaction contribution in the IXS spectra of liquid water at 301K using inelastic x-ray scattering with sub-meV energy resolution at momentum transfers 0.77<=Q<=4.20 /nm. The contribution appears due to the overlap the acoustic mode with the tail the quasi-elastic mode and is fully consistent with hydrodynamic theory. Incorporating this interaction allows us to describe the dynamic structure factor, S(Q,w), without introducing an extra mode, and may help explain earlier contradictory interpretations. The sound velocity, and relative intensity of the quasi-elastic and acoustic mode, plateau for Q>2/nm at values consistent with a viscoelastic generalization of the Landau-Placzek relation.