Chirality-induced effective magnetic field in a phthalocyanine molecule

Abstract

Chirality in organic molecules has attracted considerable attention in the fields of chemistry, biology, and spintronics. This paper reports on perpendicular magnetization hysteresis loops of a multilayer consisting of ultrathin Fe (001), chiral phthalocyanine molecule ((P)- or (M)-PbPc-DTBPh), and MgO (001). We find a chirality-dependent shift of the hysteresis loop. Unlike the previously reported bias current induced phenomena, the result shows a chirality-induced effective magnetic field in the phthalocyanine molecule in the absence of a bias current in the system. This study opens up a new direction in the emerging field of chiral molecular spintronics.