Real-space observation of emergent complexity of phase evolution in micrometer-sized IrTe$_2$ crystals

Abstract

We report complex behaviors in the phase evolution of transition-metal dichalcogenide IrTe$_2$ thin flakes, captured with real-space observations using scanning Raman microscopy. The phase transition progresses via growth of a small number of domains, which is unlikely in statistical models that assume a macroscopic number of nucleation events. Consequently, the degree of phase evolution in the thin flakes is quite variable for the selected specimen and for a repeated measurement sequence, representing the emergence of complexity in the phase evolution. In the $\sim$20-$\mu$m$^3$-volume specimen, the complex phase evolution results in the emergent coexistence of a superconducting phase that originally requires chemical doping to become thermodynamically stable. These findings indicate that the complexity involved in phase evolution considerably affects the physical properties of a small-sized specimen.