The reactivity of methanimine radical cation (H2CNH+·) and its isomer aminomethylene (HCNH2+·) with C2H4

Abstract

Experimental and theoretical studies are presented on the reactivity of methanimine and aminomethylene cations with ethene. Selective isomer generation is performed via dissociative photoionization of suitable neutral precursors and reactive cross sections and branching ratios are measured as a function of photon and collision energies.

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