Ultrafast disruptive probing: simultaneously keeping track of tens of reaction pathways

Abstract

Ultrafast science depends on different implementations of the well-known pump-probe method. Here we provide a formal description of ultrafast disruptive probing, a method in which the probe pulse disrupts a transient species that may be a metastable ion or a transient state of matter. Disruptive probing has the advantage of allowing simultaneous tracking of the yield of tens of different processes. Our presentation includes a numerical model and experimental data on multiple products resulting from the strong-field ionization of two different molecules, partially-deuterated methanol and norbornene. In combination with ion imaging and/or coincidence momentum imaging, or as complementary to atom-specific probing or ultrafast diffraction methods, disruptive probing is a particularly powerful tool for the study of strong-field laser-matter interactions.