Ultrahigh Poisson's ratio glasses

Abstract

The manner in which metallic glasses fail under external loading is known to correlate well with those glasses' Poisson's ratio $\nu$: low-$\nu$ (compressible) glasses typically feature brittle failure patterns with scarce plastic deformation, while high-$\nu$ (incompressible) glasses typically fail in a ductile manner, accompanied by a high degree of plastic deformation and extensive liquid-like flow. Since the technological utility of metallic glasses depends on their ductility, materials scientists have been concerned with fabricating high-$\nu$ glassy alloys. To shed light on the underlying micromechanical origin of high-$\nu$ metallic glasses, we employ computer simulations of a simple glass-forming model with a single tunable parameter that controls the interparticle-potential's stiffness. We show that the presented model gives rise to ultra high-$\nu$ glasses, reaching $\nu\!=\!0.45$ and thus exceeding the most incompressible laboratory metallic glass. We discuss the possible role of the so-called unjamming transition in controlling the elasticity of ultra high-$\nu$ glasses. To this aim, we show that our higher-$\nu$ computer glasses host relatively softer quasilocalized glassy excitations, and establish relations between their associated characteristic frequency, macroscopic elasticity, and mechanical disorder.