Unsteady rheo-optical measurements of uniaxially extending liquid polymers

Abstract

The viscoelastic behavior of liquid polymers changes depending on the microstructure of the polymer chains. To investigate the unsteady structural changes induced by polymer chain morphology under stress, we develop a simple rheo-optical technique combining a high-speed polarization camera and dripping-onto-substrate capillary breakup extensional rheometry (CaBER-DoS), which uniaxially extends and aligns the polymer along the stress direction. Using this technique, the viscoelastic behavior and birefringence field of an extending liquid polymer are simultaneously measured. Unlike the conditions that occur under shear-stress loading with a rotational rheometer, this technique provides a linear relation between birefringence and extensional stress. The measurements reflect the structural change in a flexible polymer (a mixed solution of PEO and CNCs) in the temporal evolution of the birefringence and orientation angle, which is a measure of the orientation state and coil-stretch transition of a polymer chain. Remarkably, within the elasto-capillary regime, the measured birefringence remains constant with a constant orientation state, while the Weissenberg number gradually increases, which provides experimental evidence of the coil-stretch transition of the polymer chain under constant extensional stress loading.