Analyzing the photoassociation spectra of ultracold 85Rb133Cs molecule in (3)3+ state

Abstract

We establish a theoretical model to analyze the photoassociative (PA) spectroscopy of (3)3+ state of 85Rb133Cs molecule. The term energy, spin-spin coupling constants and hyperfine interaction constant of nine vibrational levels in the (3)3+ state are determined. Based on the fitted term energy and rotation constant, the potential energy curve of (3)3+ state is obtained by using the RKR method which is compared with the ab initial potential curve.

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