Kekule spin-orbit dimer phase and triplon dynamics

Abstract

We derive and study a spin-orbital model for ions with $d^1$ electronic configuration on a honeycomb lattice. In this system, the directional character of $t_{2g}$ orbital leads to extensively degenerate dimerized ground states. We find that additional interactions from charge transfer processes completely lift the degeneracy and stabilize the Kekule spin-orbit dimerized phase where dimers form a kagome superlattice. For such phase, the triplon band spectrum resembles the electronic band structure of the kagome lattice and becomes topologically non-trivial in the presence of inter-dimer Dzyaloshinskii-Moriya interactions. As an experimental verification of the Kekule dimerized phase, we propose the thermal Hall experiment, which can directly uncover the topological profile of the corresponding triplon band spectrum.