QED mα7 effects for triplet states of helium-like ions
Abstract
We perform ab initio calculations of the QED effects of order mα7 for the 23S and 23P states of He-like ions. The computed effects are combined with previously calculated energies from [V. A. Yerokhin and K. Pachucki, Phys. Rev. A 81, 022507 (2010)], thus improving the theoretical accuracy by an order of magnitude. The obtained theoretical values for the 23S-23P0,2 transition energies are in good agreement with available experimental results and with previous calculations performed to all orders in the nuclear binding strength parameter Zα. For the ionization energies, however, we find some inconsistency between the Zα-expansion and all-order calculations, which might be related to a similar discrepancy between the theoretical and experimental results for the ionization energies of helium [V. Patk\'os et al., Phys. Rev. A 103, 042809 (2021)].
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