Superconductivity up to 17 K in the high-pressure rhombohedral-I phase of ReO3: a potential oxide analogy of hydride superconductors

Abstract

As an A-site-vacant perovskite-type oxide, ReO3 undergoes sequential pressure-driven structural transitions associated with the rotation of ReO6 octahedra. The rhombohedral-I phase in the pressure range of 12-39 GPa is featured by a lattice of nearly close-packed oxygen layers intercalated with Re cations, in reminiscent of the recently discovered superhydride superconductors. A combined study of first-principles calculations and transport measurements under high pressures enabled us to discover superconductivity in the rhombohedral-I phase, and it shows a dome-shaped Tc(P) with a maximum Tc of 17 K at about 30 GPa. In addition to the enhanced density of states at Fermi level compared to that of the ambient phase, the vibrations of hexagonal-close-packed oxygen lattice significantly strengthen the electron-phonon coupling, which is responsible for observed superconductivity with a relatively high Tc. The present work thus establishes a rare case among oxide superconductors that the light-element oxygen lattice plays a crucial role in inducing superconductivity.