Exploring the origins of perpendicular magnetic anisotropy in amorphous Tb-Co via changes in medium-range ordering

Abstract

Amorphous thin films of Tb$_{17}$Co$_{83}$ (a-Tb-Co) grown by magnetron co-sputtering exhibit changes in magnetic anisotropy with varying growth and annealing temperatures. The magnetic anisotropy constant increases with increasing growth temperature, which is reduced or vanishes upon annealing at temperatures above the growth temperature. The proposed explanation for this growth-induced anisotropy in high orbital moment Tb-based transition metal alloys such as a-Tb-Co is an amorphous phase texturing with preferential in-plane and out-of-plane local bonding configurations for the rare-earth and transition metal atoms. Scanning nanodiffraction performed in a transmission electron microscope (TEM) is applied to a-Tb$_{17}$Co$_{83}$ films deposited over a range of temperatures to measure relative changes in medium-range ordering (MRO). These measurements reveal an increase in MRO with higher growth temperatures and a decrease in MRO with higher annealing temperatures. The trend in MRO indicates a relationship between the magnetic anisotropy and local atomic ordering. Tilting select films between 0$^{\circ}$ and 40$^{\circ}$ in the TEM measures variations in the local atomic structure a function of orientation within the films. The findings support claims that preferential ordering along the growth direction results from temperature-mediated adatom configurations during deposition, and that oriented MRO correlates with the larger anisotropy constants.