Wavelength Dependent Nonlinear Spectroscopic Study of Third Harmonic Generation Probed by Rotational Maker Fringes Method

Abstract

Efficient third-order nonlinearities of the Zinc Oxide and Al-doped Zinc Oxide were studied by Third Harmonic Generation (Third Harmonic Generation) Maker fringes to establish the effect Aluminum of Aluminum doping(Al-doping) on the cubic nonlinearities. The addition of the Al-dopant to the Zinc Oxide crystal structure results in changes that affected the optical and nonlinear characteristics. Presented results indicate that magnitude of the third-order nonlinear susceptibility tensor was enhanced at single experimental wavelengths, however, across the broadband experimental spectrum the effect of Al-doping remained relatively constant. The observed enhancement of third-order nonlinearity was purely from the bound electronic response and the observation is attributed to increased charge carriers and spontaneous polarization in the Zinc Oxide and Al-doped Zinc Oxide crystal structure.