Grand-canonical Thermodynamic Formalism via IFS: volume, temperature, gas pressure and grand-canonical topological pressure

Abstract

We consider here a dynamic model for a gas in which a variable number of particles N ∈ N0 := N \0\ can be located at a site. This point of view leads us to the grand-canonical framework and the need for a chemical potential. The dynamics is played by the shift acting on the set of sequences := AN, where the alphabet is A := \1,2,...,r\. Introducing new variables like the number of particles N and the chemical potential μ, we adapt the concept of grand-canonical partition sum of thermodynamics of gases to a symbolic dynamical setting considering a Lipschitz family of potentials % (AN)N ∈ N0, AN: R. Our main results will be obtained from adapting well-known properties of the Thermodynamic Formalism for IFS with weights to our setting. In this direction, we introduce the grand-canonical-Ruelle operator: Lβ, μ(f)=g, when, β>0,μ<0, and \,\,\,\,\,\,\,\,\,\,\,\,\,\,g(x)= Lβ, μ(f) (x) =ΣN ∈ N0 eβ \, μ\, N \, Σj ∈ A e- \,β\, AN(jx) f(jx). We show the existence of the main eigenvalue, an associated eigenfunction, and an eigenprobability for Lβ, μ*. We can show the analytic dependence of the eigenvalue on the grand-canonical potential. Considering the concept of entropy for holonomic probabilities on × AN0, we relate these items with the variational problem of maximizing grand-canonical pressure. In another direction, in the appendix, we briefly digress on a possible interpretation of the concept of topological pressure as related to the gas pressure of gas thermodynamics.

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