Enhanced thermal stability of dielectric and energy storage properties in 0.4BCZT-0.6BTSn lead-free ceramics elaborated by sol-gel method

Abstract

Polycrystalline lead-free Ba$_{0.85}$Ca$_{0.15}$Zr$_{0.10}$Ti$_{0.90}$O$_3$ (BCZT), BaTi$_{0.89}$Sn$_{0.11}$O$_3$ (BTSn) and 0.4Ba$_{0.85}$Ca$_{0.15}$Zr$_{0.10}$Ti$_{0.90}$O$_3$-0.6BaTi$_{0.89}$Sn$_{0.11}$O$_3$ (0.4BCZT-0.6BTSn) ferroelectric ceramics were prepared via sol gel process and their structural, dielectric and energy storage properties were studied. Pure perovskite structure was confirmed by X ray diffraction analysis. The evolution of energy storage performances with temperature was studied. A Significant recoverable energy storage density of 137.86 mJ/cm$^3$ and high energy-storage efficiency of 86.19% under a moderate electric field of 30 kV/cm were achieved in the composite 0.4BCZT 0.6BTSn ceramic at 353 $^\circ$K. Moreover, excellent temperature stability (70-130 $^\circ$C) of the energy storage efficiency (less than 3%) was achieved.