Eu ions and copper selenide nanoparticles within silica sol-gel matrices

Abstract

The sol-gel technique was developed for preparation of silica glasses doped with europium and copper chalcogenide nanoparticles. A synthesis of copper compounds proceeded within the solid matrix at the different steps of the process, and features of final products can be controlled by the precursor composition and heat treatment conditions. Eu3+-ions within the silica matrix serves as a luminescent probe sensitive to the environment and a tool for studies of energy transfer between different absorption and emission centers with efficient light absorption in nanoparticles and emission by Eu3+.