Evaluation of the second virial coefficient for the Mie potential using the method of brackets

Abstract

The second virial coefficient for the Mie potential is evaluated using the method of brackets. This method converts a definite integral into a series in the parameters of the problem, in this case this is the temperature $T$. The results obtained here are consistent with some known special cases, such as the Lenard-Jones potential. The asymptotic properties of the second virial coefficient in molecular thermodynamic systems and complex fluid modeling are described in the limiting cases of $T \rightarrow 0$ and $T \rightarrow \infty$.