Orientational dynamics of anisotropic colloidal particles in a planar extensional flow

Abstract

Suspensions of anisotropic particles are commonly encountered in a wide spectrum of applications, including industrial and architectural coatings, targeted drug delivery and manufacturing of fiber-reinforced composites. A grand challenge in the field of chemical and material processing is robust production of strongly aligned fibers at the microscopic level, as this is routinely linked with enhanced mechanical properties at the macroscopic level. While the investigation of the microstructure of anisotropic colloids in shear flows has garnered a lot of theoretical and experimental attention, the case of extensional flow remains poorly understood due to several experimental challenges. In this article, we present a theoretical framework for predicting the steady and transient orientations of anisotropic particles in a flowing liquid undergoing precisely defined steady and time-dependent planar extensional flow at the stagnation point of a Stokes trap device. In particular, we analytically solve the Fokker-Planck equation for estimating the probability distribution function describing the orientation dynamics of rod-like objects as a function of flow strength (Peclet number, Pe) and probing frequency (Deborah number, De). The theoretical results are compared with recent experiments and reasonable agreement is found. We also discuss the challenges involved in obtaining a full closed-form solution for the transient dynamics of anisotropic particles in oscillatory time-dependent extensional flow. Overall, our theoretical framework provides a way to compare the orientation dynamics of rod-like particles with experiments that have been performed using a new experimental technique involving the Stokes trap and precise flow-control over the orientation of particles.