The curious case of CO$_2$ dissociation on Cu(110)

Abstract

Dissociation of CO$_2$ on copper surfaces, a model system for understanding the elementary steps in catalytic conversion of CO$_2$ to methanol has been extensively studied in the past. It is thought to be reasonably well-understood from both experiments and theory. In contrast, our findings reported here suggest a different picture. Using molecular beam surface scattering methods, we measure the initial dissociation probabilities ($S_{\rm 0}$) of CO$_2$ on a flat, clean Cu(110) surface under ultra-high vacuum conditions. The observed $S_{\rm 0}$ ranges from $3.9\times10^{-4}$ to $1.8\times10^{-2}$ at incidence energies of 0.64 eV to 1.59 eV with a lower limit to dissociation barrier estimated to be around 2.0 eV, much larger than that understood previously. We discuss the possible reasons behind such large differences in our results and previous work. These findings are anticipated to be extremely important for obtaining a correct understanding of elementary steps in CO$_2$ dissociation on Cu surfaces.