Graphene-like nanoribbons connected by four-/five- membered rings on pentacene/picene precursors, Au(110) surface

Abstract

The rapid development of fabrication of functional high-quality graphene-like nanoribbons has increasingly reliant on integration of diverse nanofabrication platforms. The demand for innovative techniques to enable the exploration and precise manipulation of graphene-like nanoribbons. Herein, we present an on-surface synthesis approach for graphene-like nanoribbons, achieved through the self-assembly and annealing of pentacene/picene monomers on an one-dimensional(1D) Au(110) substrate. Scanning tunneling microscope(STM) analysis reveals that the formation of four- and eight- membered rings between adjacent molecules. Furthermore, we demonstrate a technique for manipulating pentacene dimer without breaking structural integrity by STM tip manipulation. Our results exhibit a potential platform for the development of next-generation graphene-based quantum computing architectures, as well as a technique for fabricating functional graphene-like nanoribbons with exceptional precision.