Local dynamics and detection of topology in spin-1 chains

Abstract

Antiferromagnetic spin-1 chains host the celebrated symmetry protected topological Haldane phase, whose spin-1/2 edge states were evidenced in bulk by, e.g., Electron Spin Resonance (ESR). Recent success in assembling effective spin-1 antiferromagnetic chains from nanographene and porphyrin molecules opens the possibility of local, site-by-site, characterization. The nascent technique of combined ESR-STM is able to measure the spin dynamics with atomic real-space resolution, and could fully reveal and manipulate the spin-1/2 degree of freedom. In this work, we combine exact diagonalization and DMRG to investigate the local dynamic spin structure factor of the different phases of the bilinear-biquadratic Hamiltonian with single-ion anisotropy in presence of an external magnetic field. We find that the signature of the Haldane phase is a low-energy peak created by singlet-triplet transitions in the edge-state manifold. We predict that the signature peak is experimentally observable, although for chains of length above N = 30 its energy should be first tuned by application of external magnetic field. We fully characterize the peak in real-space and energy, and further show its robustness to weak anisotropy and a relevant range of temperatures.