Local distortion driven magnetic phase switching in pyrochlore $Yb_2(Ti_{1-x}Sn_x)_2O_7$

Abstract

While it is commonly accepted that the disorder induced by magnetic ion doping in quantum magnets usually generates a rugged free-energy landscape resulting in slow or glassy spin dynamics, the disorder/distortion effects associated with non-magnetic ion sites doping are still illusive. Here, using AC susceptibility measurements, we show that the mixture of Sn/Ti on the non-magnetic ion sites of pyrochlore $Yb_2(Ti_{1-x}Sn_x)_2O_7$ induces an antiferromagnetic ground state despite both parent compounds, $Yb_2Ti_2O_7$, and $Yb_2Sn_2O_7$, order ferromagnetically. Local structure studies through neutron total scattering reveals the local distortion in the non-magnetic ion sites and its strong correlation with the magnetic phase switching. Our study, for the first time, demonstrates the local distortion as induced by the non-magnetic ion site mixture could be a new path to achieve magnetic phase switching, which has been traditionally obtained by external stimuli such as temperature, magnetic field, pressure, strain, light, etc.