Quantitative measurement of figure of merit for transverse thermoelectric conversion in Fe/Pt metallic multilayers

Abstract

This study presents a measurement method for determining the figure of merit for transverse thermoelectric conversion ($ z_\mathrm{T}T $) in thin film forms. Leveraging the proposed methodology, we comprehensively investigate the transverse thermoelectric coefficient ($ S_\mathrm{T} $), in-plane electrical conductivity ($ \sigma_{yy} $), and out-of-plane thermal conductivity ($ \kappa_{xx} $) in epitaxial and polycrystalline Fe/Pt metallic multilayers. The $ \kappa_{xx} $ values of multilayers with a number of stacking repetitions ($ N $) of 200 are lower than those of FePt alloy films, indicating that the multilayer structure effectively contributes to the suppression of $ \kappa_{xx} $. $ z_\mathrm{T}T $ is found to increase with increasing $ N $, which remarkably reflects the $ N $-dependent enhancement of the $ S_\mathrm{T} $ values. Notably, $ S_\mathrm{T} $ and $ \sigma_{yy} $ are significantly larger in the epitaxial multilayers than those in the polycrystalline counterparts, whereas negligible differences in $ \kappa_{xx} $ are observed between the epitaxial and polycrystalline multilayers. This discrepancy in $ \sigma_{yy} $ and $ \kappa_{xx} $ with respect to crystal growth is due to the different degree of anisotropy in electron transport between epitaxial and polycrystalline multilayers, and epitaxial growth can lead to an enhancement of $ z_\mathrm{T}T $ in the multilayers. This study is the first demonstration in the evaluation of $ z_\mathrm{T}T $ in thin film forms, and our proposed measurement technique reveals the transverse thermoelectric properties inherent to multilayers.