Free-standing cubic gauche nitrogen stable at 760 K under ambient pressure

Abstract

Cubic gauche nitrogen (cg-N) has received wide attention due to its high energy density and environmental friendliness. However, existing synthesis methods for cg-N predominantly rely on the high-pressure techniques, or the utilization of nanoconfined effects using highly toxic and sensitive sodium azide as precursor, which significantly restrict the practical application of cg-N as high energy density materials (HDEM). Here, based on the first-principles simulations, we find that the adsorption of potassium on the cg-N surface exhibits superior stabilization compared to sodium. Then, we chose the safer potassium azide as raw material for synthesizing cg-N. Through plasma-enhanced chemical vapor deposition treatment, the free-standing cg-N was successfully synthesized without the need of high-pressure and nanoconfined effects. Importantly, it demonstrates excellent thermal stability up to 760 K, and then a rapid and intense thermal decomposition occurs, exhibiting typical behaviors of HDEM thermal decomposition. Our work has significantly promoted the practical application of cg-N as HDEM.