Transition frequencies, isotope shifts, and hyperfine structure in $4s \rightarrow 4p$ transitions of Ti$^+$ ions

Abstract

We have measured transition frequencies, isotope shifts and hyperfine structure splittings in the $3 d^{2}\left({ }^{3\!}F\right) 4 s\,{ }^{4} F_J\rightarrow 3 d^{2}\left({ }^{3\!} F\right) 4 p \,^{4} G_{J+1}$ transitions in Ti$^+$ ions for $J=\frac{3}{2},\, \frac{5}{2},\, \frac{7}{2}$ using collinear laser spectroscopy. Ions were generated by laser ablation in a buffer gas atmosphere and extracted into vacuum through a nozzle and a pair of radiofrequency (RF) funnels. The obtained results are of interest as reference values for on-line measurements of short-lived titanium isotopes and for astrophysical searches for temporal or spatial variations of the fine structure constant $\alpha$ using quasar absorption spectra.