Grain growth phenomenon during pressure-induced phase transformations at room temperature

Abstract

Significant grain growth is observed during the high-pressure phase transformations (PTs) at room temperature within an hour for various materials. However, no existing theory explains this phenomenon since nanocrystals do not grow at room temperature even over a time span of several years because of slow diffusion. Here, we suggest a multistep mechanism for the grain growth during $\alpha\rightarrow\omega$ PT in Zr. Phase interfaces and grain boundaries (GBs) coincide and move together under the action of a combined thermodynamic driving forces. Several intermediate steps for such motion are suggested and justified kinetically. Nonhydrostatic stresses due to volume reduction in the growing $\omega$ grain promote continuous growth of the existing $\omega$ grain instead of a new nucleation at other GBs. In situ synchrotron Laue diffraction experiments confirm the main predictions of the theory. The suggested mechanism provides a new insight into synergistic interaction between PTs and microstructure evolution.