Near-room-temperature ferrimagnetism and half-metallicity in disordered Ca1.5La0.5MnRuO6

Abstract

The electron spin polarization on half-metallic double-perovskites is usually conditioned to the ordered rock-salt arrangement of the transition-metal ions along the lattice. In this work, we investigate a polycrystalline sample of the Ca1.5La0.5MnRuO6 compound by employing x-ray powder diffraction, high resolution transmission electron microscopy, x-ray absorption and magnetic circular dichroism at the Mn-L2,3 and Ru-M2,3 edges, magnetometry, electrical transport and first principles calculations in order to show that this is a fully disordered material exhibiting near room temperature ferrimagnetism and half-metallic conductivity, with significant intergrain tunneling magnetoresistance. These unprecedented results are compared to those of archetypical ordered double-perovskites, and discussed in terms of the Mn and Ru valences and their orbital hybridization.