Structural and Thermoelectric Properties of Al$_{1+x}$Fe$_{2-y}$M$_y$B$_2$ (M=Ag, Ni, Sb, Ga, and Ge) Intermetallic Borides

Abstract

AlFe$_2$B$_2$, a ternary transition metal boride doped with Ag, Ni, Sb, Ga, and Ge was investigated for the phase constituents, microstructure, and thermoelectric properties. The parent compound with 20\% excess Al (Al$_{1.2}$Fe$_2$B$_2$) prepared by vacuum arc melting contains orthorhombic AlFe$_2$B$_2$ and FeB upon doping form additional phases such as Ag$_5$Al, AlNi$_3$, Al$_3$Ni$_2$, AlSb, and AlB$_2$. The structural parameters of the AlFe$_2$B$_2$ phase in Ag, Ni, and Sb-doped samples are nearly the same as the un-doped one. The lattice parameters and cell volume increase noticeably in Ga and Ge-doped compounds. The Ga-doped sample shows only FeB as a secondary phase; however, the AlB$_2$ phase is observed in Ge-doped AlFe$_2$B$_2$. The microstructure investigated in FEG-SEM with EDS shows the AlFe$_2$B$_2$ matrix is chemically homogenous in all samples, except the Ga-doped one, with uniformly distributed single or multiple secondary phases. The DSC-TG results show that all the dopants decrease the AlFe$_2$B$_2$ phase peritectic decomposition reaction temperature, indicating the structure destabilizes. The thermoelectric properties measured show that AlFe$_2$B$_2$ is an n-type compound with electrical conductivity in the range of 0.35-0.46$\times$10$^6$ S/m. The addition of Ag, Ni, Ga, and Ge marginally alters the Seebeck and electrical conductivity. The noticeable improvement in Seebeck coefficient and with negligible change in electrical conductivity resulted in a highest power factor of 0.4 mW/mK$^2$ for Sb-doped sample. The thermal conductivity of AlFe$_2$B$_2$, which is in the range of 6.4-9.1 W/m-K between 300 to 773\,K, decreases with Sb doping to 5.2-8.5 W/m-K resulting in a maximum zT of 0.04 at 773K.