Ultrafast core-to-core luminescence in BaF$_2$-LaF$_3$ single crystals

Abstract

This study investigates the mechanisms underlying ultrafast cross-luminescence observed in BaF$_2$ crystals doped with LaF$_3$. We identified an ultrafast luminescent component with a decay time of approximately 150 ps, which emerges under excitation energies exceeding 24 eV as a novel radiative recombination process between electrons in the 5p core band of Ba2+ and holes in the 5p core band of La$^{3+}$. Ab initio calculations support this hypothesis, showing that the energy levels of the core bands facilitate such transitions. The findings indicate that BaF$_2$-LaF$_3$ scintillators hold significant promise for applications in time-of-flight tomography.