Influence of Phase Segregation on the Hysteresis of Perovskite Solar Cells

Abstract

Organic-inorganic hybrid perovskite solar cells (PSC) have demonstrated impressive performance improvement. Among the various characteristics, the time-dependent current-voltage (J-V) hysteresis allows a direct exploration of various critical phenomena that affect the stability of PSCs. The hysteresis is associated with various spatial heterogeneity-related phenomena, including lifetime, bandgap, and phase segregation. We investigate these phenomena through numerical simulations and quantify how the spatial non-uniformity in the perovskite active layer impacts the hysteresis. Further, we correlate the time dependent device degradation with the hysteresis trends in terms of ion density and effective carrier lifetime.