Rapid Vapor-Assisted Solution Process of Metal-Organic Chalcogenides for High-Performance Light-Emitting Diodes

Abstract

Metal-organic chalcogenides (MOCs), robust crystalline assemblies composed of coinage metals, chalcogens and organic ligands, are typically synthesized via prolonged, high temperature tarnishing of vacuum-deposited metal films with organochalcogen precursors. The prolonged exposure to high temperatures and the necessity for direct vacuum deposition of silver can induce damage to the underlying films, posing significant challenges to the fabrication of optoelectronic devices, despite their cost-effectiveness and chemical robustness. This study introduces vapor-assisted solution processing, a novel chemical vapor deposition method, enabling remarkably rapid fabrication of luminescent MOC films. Furthermore, the first MOC-based light-emitting diodes (MOCLEDs) are realized, achieving an external quantum efficiency (EQE) approaching 0.1% and electroluminescence peaking at 633 nm. These results highlight the potential of MOCs as next-generation emitters for displays and solid-state lighting. This work offers a promising fabrication strategy and insights for advancing MOCLEDs and expanding their optoelectronic potential.