Carbon-Nanotube/$\beta$-Ga$_2$O$_3$ Heterojunction PIN Diodes

Abstract

$\beta$-Ga$_2$O$_3$ is gaining attention as a promising semiconductor for next-generation high-power, high-efficiency, and high-temperature electronic devices, thanks to its exceptional material properties. However, challenges such as the lack of viable p-type doping have hindered its full potential, particularly in the development of ambipolar devices. This work introduces a novel heterojunction diode (HD) that combines p-type carbon nanotubes (CNTs) with i/n-type $\beta$-Ga$_2$O$_3$ to overcome these limitations. For the first time, a CNT/$\beta$-Ga$_2$O$_3$ hetero-p-n-junction diode is fabricated. Compared to a traditional Schottky barrier diode (SBD) with the same $\beta$-Ga$_2$O$_3$ epilayer, the CNT/$\beta$-Ga$_2$O$_3$ HD demonstrates significant improvements, including a higher rectifying ratio ($1.2 \times 10^{11}$), a larger turn-on voltage (1.96 V), a drastically reduced leakage current at temperatures up to 300 {\deg}C, and a 26.7% increase in breakdown voltage. Notably, the CNT/$\beta$-Ga$_2$O$_3$ HD exhibits a low ideality factor of 1.02, signifying an ideal interface between the materials. These results underline the potential of CNT/$\beta$-Ga$_2$O$_3$ heterojunctions for electronic applications, offering a promising solution to current limitations in $\beta$-Ga$_2$O$_3$-based devices.