Composition-Dependent Thermoelectric Properties of Hybrid Tin Perovskites (CH3NH3)xCs1-xSnI3: Insights into Electrical and Thermal Performance

Abstract

This work presents a comprehensive investigation of the thermoelectric properties of bulk hybrid perovskites with the general formula MAxCs1-xSnI3 (0 < x < 1). A series of bulk samples were synthesized and systematically characterized to explore the relationship between composition, microstructure, and thermoelectric performance. Compositions with intermediate MA+ content (x = 0.2 and x = 0.5) show an optimal balance between electrical conductivity and Seebeck coefficient, yielding high power factor values (0.6 - 0.7 muW/cmK2 at 423 K) and favorable thermoelectric performance with zT values up to 0.06. In contrast, compositions with MA+ contents (x = 0, x = 0.6, and x = 0.8) exhibit lower thermoelectric performance due to reduced Seebeck coefficients or suppressed conductivity. MASnI3 shows promising low-temperature thermoelectric performance with a maximum $zT$ of 0.10 at 423 K, attributed to its rapidly increasing Seebeck coefficient. These findings highlight the importance of microstructural control and composition optimization in the development of hybrid perovskites for thermoelectric applications.