Hybridization theory for plasmon resonance in metallic nanostructures

Abstract

In this paper, we investigate the hybridization theory of plasmon resonance in metallic nanostructures, which has been validated by the authors in [31] through a series of experiments. In an electrostatic field, we establish a mathematical framework for the Neumann-Poincar\'{e}(NP) type operators for metallic nanoparticles with general geometries related to core and shell scales. We calculate the plasmon resonance frequency of concentric disk metal nanoshells with normal perturbations at the interfaces by the asymptotic analysis and perturbation theory to reveal the intrinsic hybridization between solid and cavity plasmon modes. The theoretical finding are convincingly supported by extensive numerical experiments. Our theory corroborates and strengthens that by properly enriching the materials structures as well as the underlying geometries, one can induce much richer plasmon resonance phenomena of practical significance.