Improving photovoltaics by adding extra terminals to extract hot carriers

Abstract

Photovoltaic cells usually have two terminals, one collecting electrons and the other collecting holes. Can more terminals improve such solar cells? Energy-filtering terminals could collect "hot" carriers (electrons or holes not yet relaxed to the band edge), with other terminals for low-energy carriers. For collection faster than carrier-phonon relaxation, we predict four-terminal cells with higher power output than optimal two-terminal cells -- more than 40% higher for fast carrier collection. Similar effects will occur in multi-terminal thermoelectrics exploiting non-equilibrium distributions

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