Spontaneous Coulomb fissions of drops on lubricated surfaces

Abstract

Charged water drops are more widespread than commonly acknowledged. For example, raindrops typically carry charges of order Q ~ 1 pC, while routine pipetting in the laboratory produces drops with Q ~ 50 pC. Here, we show that such modest charging can spontaneously generate periodic Coulomb fissions for evaporating water drops on lubricated surfaces, with more than 60 successive cycles observed over 30 min. Interestingly, the underlying instability can be quantitatively predicted by two fissility thresholds: one marking the onset of drop elongation and another triggering fission. Each fission culminates with a fine liquid jet that disintegrates into 40-50 microdroplets, expelled within microseconds. The phenomenon spans an extraordinary range of length scales (from millimetres to microns) and time scales (hour to microseconds), with broad potential applications ranging from nanoscale fabrication to electrospray ionization.