Engineering Biquadratic Interactions in Spin-1 Chains by Spin-1/2 Spacers

Abstract

Low-dimensional quantum systems host a variety of exotic states, such as symmetry-protected topological ground states in spin-1 Haldane chains. Real-world realizations of such states could serve as practical quantum simulators for quantum phases if the interactions can be controlled. However, many proposed models, such as the Affleck-Kennedy-Lieb-Tasaki (AKLT) state, require unconventional forms of spin interactions beyond standard Heisenberg terms, which do not naturally emerge from microscopic (Coulomb) interactions. Here, we demonstrate a general strategy to induce a biquadratic term between two spin-1 sites and to tune its strength $β$ by placing pairs of spin-1/2 spacers in between them. $β$ is controlled by the ratio of the Heisenberg couplings between the spin-1 sites and the spacer spins, and between the spacer spins themselves. Increasing this ratio increases the magnitude of $|β|$ and decreases the correlation length of edge states. Detailed atomistic calculations reveal that chains of nanographene flakes with 22 and 13 atoms, respectively, which could be realized by state-of-the-art bottom-up growth technology, yield precisely the couplings required to approach the AKLT state. These findings deliver a blueprint for engineering unconventional interactions in bottom-up synthesized quantum simulators.