Nanorod Pair Complexes Manipulated via Magnetic Casimir Forces

Abstract

Controlling nanoscale interactions to suppress aggregation from short-range attractive forces is a key problem in nanoengineering. Here, we demonstrate a route to modulate Casmir-Lifshitz interactions between anisotropic nanoparticles with the magnetic fluids. By semi-classical quantum electrodynamics, we study ground state dispersion forces for cylindrical dielectric nanorods made of polystyrene (PS), and zinc oxide (ZnO) embedded in toluene-based host media with gold-coated magnetite nanoparticles and also predict magnetic contributions to the non-retarded excited state interaction. The variation in magnetic permeability enables tuning between repulsive and attractive interaction and a thermally unstable and measurable magnetic Casimir traps are predicted between a pair of ZnO-PS nanoparticles whose equilibrium position can be modulated over an order of magnitude with a small variation in the size of the magnetite nanoparticle. This provides an alternative magnetic Casimir-effect pathway to reversibly tune quantum electromagnetic forces at the nanoscale for assembly and enhancement of colloidal stability.