Quasistatic response for nonequilibrium processes: evaluating the Berry potential and curvature

Abstract

We investigate how introducing slow, time-dependent perturbations to a steady, nonequilibrium process alters the expected (excess) values of important observables, such as the dynamical activity and entropy flux. When we make a cyclic thermodynamic transformation, the excesses are described in terms of a (geometric) Berry phase with corresponding Berry potential and Berry curvature quantifying the response. Focussing on Markov jump processes, we show how a non-zero Berry curvature leads to a breakdown of the thermodynamic Maxwell relations and of the Clausius heat theorem. We also present a variant of the Aharonov-Bohm effect in which the parameters follow a curve with vanishing Berry curvature, but the system still experiences a nonzero Berry phase. Finally, we identify (sufficient) no-localization conditions in terms of mean first-passage times under which the corresponding Berry potentials and curvatures vanish at absolute zero, extending, for arbitrary driving, e.g., the case of vanishing heat capacity as for the Nernst postulate.