Calibrated Plane--Convex Microcavity for Room-Temperature Polaritons with Geometric \(g\)-Scaling

Abstract

We present a plane--convex open microcavity that supports room-temperature polariton spectroscopy and offers a simple geometric handle on the coupling rate. The effective length (Leff) is absolutely calibrated from the free-spectral range, and piezo tuning is performed at near-normal incidence (k!≈!0) to avoid angle-induced degradation. Using spin-coated PEA2PbI4 quasi-2D perovskites, we observe clear anti-crossings in reflection, with vacuum Rabi splittings up to 71~meV (reflection) and 87~meV (PL) near Leff!≈!3~μm. A linewidth-corrected analysis converts the apparent splitting into the coherent exciton--photon coupling rate g, revealing a robust geometric scaling g Leff-1/2 across multiple longitudinal orders and spatial sites, consistent with the filled-mode thin-film limit where the transverse area cancels in the mode volume. The platform establishes a compact, broadly compatible testbed for room-temperature polaritons and provides a practical design rule: shortening Leff is a reliable geometric lever to strengthen collective coupling in plane--convex microcavities.

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