Fine and Hyperfine Interactions with Multi-level Spin Relaxation of the purified Giese-Salt in Veterinary Medicine: Prussian Blue Compound Ammonium-Ferric-Hexacyano-Ferrate
Abstract
Ammonium ferric hexacyanoferrate is a veterinary-medical milestone and antidote against radiocesium, well-known as Giese-salt after the Chernobyl disaster fed to domestic and wild animals, which shows even a rich interplay of properties in nanostructural chemistry and ferromagnetism. Among the broad analytical techniques, the ambivalence of macroscopic micrometer-sized agglomerates and nanoparticle sizes, a suggested enlarged Fe(II)-C-Fe(III) bond length by Fe K-edge XAFS results and multi-level spin relaxation in 57Fe M\"ossbauer spectroscopy are highlighted. This sets this underestimated compound in a new light, e.g., for modern biomedicine and biofunctionality, extending its essential importance in addition to hypothetical future nuclear incidents
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