Casimir-force spectroscopy of broadband optical response

Abstract

Broadband optical response governs light-matter interactions across photonics, plasmonics, thermal radiation, and quantum fluctuation electrodynamics, yet determining a continuous dielectric function over many decades in frequency typically requires combining multiple spectroscopies, extrapolations, and material models. Here we show that quantum-fluctuation forces provide a route to broadband optical characterization. Casimir interactions depend on the dielectric response of materials across the electromagnetic spectrum, but this information is encoded through Lifshitz theory in a spectrally weighted and nontrivial way. By training physics-constrained supervised learning models on synthetic dielectric spectra and their corresponding Casimir force curves, we invert this relationship and reconstruct the complex permittivity of materials over more than seven orders of magnitude in frequency from force-distance data. The reconstruction reveals a direct separation-frequency correspondence: large separations constrain low-frequency free-carrier response, whereas shorter separations encode higher-frequency resonant structure. Applying the method to measured force gradients identifies the current experimental limits imposed by measurement noise, restricted separation range, and model complexity. These results establish fluctuation-induced forces as a spectrally weighted route to broadband optical characterization and define the experimental and physical limits that govern what spectral information is accessible from near-field quantum electromagnetic measurements.